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- W2078897111 abstract "Inverse type Diels-Alder reactions of ethyl (E)-3-(1,3-benzothiazol-2-yl)-3-cyanopropenoate (2) as 1-aza-1,3-butadiene are described. The diene (2), bearing electron-withdrawing ester group at diene 4-position, reacts with electron-rich dienophiles (3a-d) under extremely mild conditions to give corresponding cycloadducts (4a-d) with regio- and endo-selectivities. Treatment of 2 with electron-donating allyl alcohols (6a-d) causes tandem transesterification and intramolecular cycloaddition to afford cis-fused polycyclic systems (7a-d) in a single step." @default.
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- W2078897111 date "1996-01-01" @default.
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- W2078897111 title "Inter- and intramolecular Diels-Alder reactions using a highly reactive 1-aza-1,3-butadiene, ethyl (E)-3-(1,3-benzothiazol-2-yl)-3-cyanopropenoate" @default.
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- W2078897111 doi "https://doi.org/10.1016/0040-4020(95)01033-5" @default.
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