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- W2078902651 startingPage "281" @default.
- W2078902651 abstract "Allyl alcohol was polymerized by radiation under various conditions. The limiting conversions were about 30% in bulk, 35% when containing 0.03 mole fraction AlCl3 and 50% when water was contained at 27% (v/v). Irradiation was done with Co-60 gamma rays at room temperature and under vacuum. The presence of oxygen did not cause any change in the reaction rate. Molecular weights were determined by viscosity and cryoscopic methods. K and α values were found to be 3.57×10−4 and 0.62 for solutions in methanol at 25°C. The polymers up to about 10% conversion were viscous liquids having microcapsular structures: at high conversions, they became hard and glassy. The microencapsulated structures were also retained in solutions in methanol, acetone, and isopropyl alcohol. The samples were insoluble in water, benzene, and toluene." @default.
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- W2078902651 date "1989-04-01" @default.
- W2078902651 modified "2023-09-27" @default.
- W2078902651 title "Polymerization of Allyl Alcohol by Radiation to Obtain Microencapsulated Structure" @default.
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- W2078902651 doi "https://doi.org/10.1295/polymj.21.281" @default.
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