Matches in SemOpenAlex for { <https://semopenalex.org/work/W2078903774> ?p ?o ?g. }
Showing items 1 to 68 of
68
with 100 items per page.
- W2078903774 endingPage "3690" @default.
- W2078903774 startingPage "3690" @default.
- W2078903774 abstract "Reaction of Pt(S2PPh2)2 with tertiary phosphines (PPh3, PMePh2, PMe2Ph) gives crystalline 1 : 1 and 1 : 2 adducts. With triphenylarsine or triphenylstibine, only 1 : 1 adducts can be isolated and with pyridine, i.r. evidence indicates that the 1 : 1 adduct is only stable in solution in the presence of an excess of pyridine. As reported earlier for the analogous palladium compounds, the 1 : 2 adducts rapidly dissociate to the 1 : 1 compounds in non-polar solvents (benzene or carbon disulphide); however, it is now found that they can be stabilised in more polar solvents (dichloromethane or nitromethane). Conductivity measurements in the latter suggests all these 1 : 2 adducts have a four-co-ordinate ionic structure and this is confirmed by an X-ray analysis of [Pd(S2PPh2)(PEt3)2]S2PPh2. An X-ray analysis on [Pd(S2PPh2)2(PPh3)] suggests a four-co-ordinate monomeric structure for the 1 : 1 compounds with uni- and bi-dentate co-ordination of dithioacid ligands. Finally, an empirical i.r. method for distinguishing unidentate, bidentate, and ionic modes of co-ordination of the diphenylphosphinodithioato-group to platinum and palladium is discussed." @default.
- W2078903774 created "2016-06-24" @default.
- W2078903774 creator A5023110885 @default.
- W2078903774 creator A5060244445 @default.
- W2078903774 creator A5062881319 @default.
- W2078903774 date "1971-01-01" @default.
- W2078903774 modified "2023-09-30" @default.
- W2078903774 title "Metal complexes of sulphur ligands. Part II. Reaction of bis(diphenylphosphinodithioato)-platinum(II) and -palladium(II) with ligands containing group VB atoms" @default.
- W2078903774 doi "https://doi.org/10.1039/j19710003690" @default.
- W2078903774 hasPublicationYear "1971" @default.
- W2078903774 type Work @default.
- W2078903774 sameAs 2078903774 @default.
- W2078903774 citedByCount "23" @default.
- W2078903774 countsByYear W20789037742012 @default.
- W2078903774 countsByYear W20789037742020 @default.
- W2078903774 crossrefType "journal-article" @default.
- W2078903774 hasAuthorship W2078903774A5023110885 @default.
- W2078903774 hasAuthorship W2078903774A5060244445 @default.
- W2078903774 hasAuthorship W2078903774A5062881319 @default.
- W2078903774 hasConcept C108204754 @default.
- W2078903774 hasConcept C145148216 @default.
- W2078903774 hasConcept C155647269 @default.
- W2078903774 hasConcept C161790260 @default.
- W2078903774 hasConcept C178516000 @default.
- W2078903774 hasConcept C178790620 @default.
- W2078903774 hasConcept C179104552 @default.
- W2078903774 hasConcept C185592680 @default.
- W2078903774 hasConcept C2182769 @default.
- W2078903774 hasConcept C2779485729 @default.
- W2078903774 hasConcept C2780400988 @default.
- W2078903774 hasConcept C2780471494 @default.
- W2078903774 hasConcept C502130503 @default.
- W2078903774 hasConcept C518104683 @default.
- W2078903774 hasConcept C544153396 @default.
- W2078903774 hasConceptScore W2078903774C108204754 @default.
- W2078903774 hasConceptScore W2078903774C145148216 @default.
- W2078903774 hasConceptScore W2078903774C155647269 @default.
- W2078903774 hasConceptScore W2078903774C161790260 @default.
- W2078903774 hasConceptScore W2078903774C178516000 @default.
- W2078903774 hasConceptScore W2078903774C178790620 @default.
- W2078903774 hasConceptScore W2078903774C179104552 @default.
- W2078903774 hasConceptScore W2078903774C185592680 @default.
- W2078903774 hasConceptScore W2078903774C2182769 @default.
- W2078903774 hasConceptScore W2078903774C2779485729 @default.
- W2078903774 hasConceptScore W2078903774C2780400988 @default.
- W2078903774 hasConceptScore W2078903774C2780471494 @default.
- W2078903774 hasConceptScore W2078903774C502130503 @default.
- W2078903774 hasConceptScore W2078903774C518104683 @default.
- W2078903774 hasConceptScore W2078903774C544153396 @default.
- W2078903774 hasLocation W20789037741 @default.
- W2078903774 hasOpenAccess W2078903774 @default.
- W2078903774 hasPrimaryLocation W20789037741 @default.
- W2078903774 hasRelatedWork W2026948689 @default.
- W2078903774 hasRelatedWork W2046617025 @default.
- W2078903774 hasRelatedWork W2048500280 @default.
- W2078903774 hasRelatedWork W2051658337 @default.
- W2078903774 hasRelatedWork W2057561984 @default.
- W2078903774 hasRelatedWork W2077961314 @default.
- W2078903774 hasRelatedWork W2078697690 @default.
- W2078903774 hasRelatedWork W2096116918 @default.
- W2078903774 hasRelatedWork W2163634197 @default.
- W2078903774 hasRelatedWork W2169367981 @default.
- W2078903774 isParatext "false" @default.
- W2078903774 isRetracted "false" @default.
- W2078903774 magId "2078903774" @default.
- W2078903774 workType "article" @default.