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- W2078904569 abstract "Diazo compounds, which can be accessed directly from azides by deimidogenation, are shown to be extremely versatile dipoles in 1,3-dipolar cycloaddition reactions with a cyclooctyne. The reactivity of a diazo compound can be much greater or much less than its azide analog, and is enhanced markedly in polar-protic solvents. These reactivities are predictable from frontier molecular orbital energies. The most reactive diazo compound exhibited the highest known second-order rate constant to date for a dipolar cycloaddition with a cycloalkyne. These data provide a new modality for effecting chemoselective reactions in a biological context." @default.
- W2078904569 created "2016-06-24" @default.
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- W2078904569 date "2012-01-01" @default.
- W2078904569 modified "2023-10-17" @default.
- W2078904569 title "Diazo compounds as highly tunable reactants in 1,3-dipolar cycloaddition reactions with cycloalkynes" @default.
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- W2078904569 doi "https://doi.org/10.1039/c2sc20806g" @default.
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