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- W2078906678 abstract "On the Temperature Dependence of the 13C-NMR. Spectra of [5-6-η-(1Z,5E)-Cyclooctadien] and of (lZ, 5E)-Cyclooctadiene The activation parameters of the conformational ring inversion process (simultaneous rotation around the C(3), C(4) and C(7), C(8) bonds; cf. Scheme 1) of the title compounds (1 and 2, respectively) have been determined between 275 L and 155 K by a complete line shape analysis of the temperature dependent proton noise-modulated decoupled 13C-NMR. spectra of 1 and 2. The temperature dependence of the rates (k(1) and k(2), respectively) of the inversion process can be described by the following equations (no influence of the solvents was observed; Ea in J/mol): . Further data are given in Tables 1 and 2. The carbonyl groups of the complex 1 show at 180 K, where the ring inversion process is frozen out, a single line at 211 ppm, i. e. the coalescence temperature of the carbonyl groups must be < 180 K." @default.
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- W2078906678 date "1978-07-12" @default.
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- W2078906678 title "Über die Temperaturabhängigkeit der13C-NMR.-Spektren von [5-6-η-(1Z, 5E)-Cyclooctadien]tetracarbonyleisen und (1Z, 5E)-Cyclooctadien" @default.
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- W2078906678 doi "https://doi.org/10.1002/hlca.19780610517" @default.
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