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- W2078911282 abstract "The bis[4-(n-CmH2m+1O)-5-(p-C14H29C6H4N=N)]-substituted N,N′-salicylidenediamines H2[LN(m,14)] (N = 1: 1,2-diaminoethane; N = 2: 1,3-diaminopropane; N = 3: 1,3-diamino-2,2-dimethylpropane; m = 6 or 18) have been synthesized. Both the N = 2 and 3 series of compounds display a smectic C (SmC) mesophase, with clearing points well below 100 °C. By treating the H2[LN(m,14)] ligands with an NiII salt, liquid crystalline mononuclear complexes with “unconventional” (lateral-tailed) molecular shape form. These Ni[LN(m,14)] complexes, showing nematic and smectic disordered phases, are stable over a quite large temperature range and have been characterized by different spectroscopic techniques. The newly synthesized mesogens exhibit lower transition temperatures and higher thermal stability than homologous complexes Ni[LN(14)] with a “conventional” rod-like molecular geometry." @default.
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- W2078911282 date "1999-08-01" @default.
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- W2078911282 title "Synthesis, Mesomorphism, and Spectroscopic Characterization of Bis[4-(n-alkoxy)-5-(p-n-tetradecylphenylazo)]-Substituted (N,N′-Salicylidenediaminato)nickel(II) Complexes" @default.
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- W2078911282 doi "https://doi.org/10.1002/(sici)1099-0682(199908)1999:8<1367::aid-ejic1367>3.0.co;2-m" @default.
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