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• W2078921621 abstract "The Cu–Ni nanoalloy phase diagram respecting the nanoparticle size as an extra variable was calculated by the CALPHAD method. The samples of the Cu–Ni nanoalloys were prepared by the solvothermal synthesis from metal precursors. The samples were characterized by means of dynamic light scattering (DLS), infrared spectroscopy (IR), inductively coupled plasma optical emission spectroscopy (ICP/OES), transmission electron microscopy (TEM, HRTEM), and differential scanning calorimetry (DSC). The nanoparticle size, chemical composition, and Cu–Ni nanoparticles melting temperature depression were obtained. The experimental temperatures of melting of nanoparticles were in good agreement with the theoretical CALPHAD predictions considering surface energy. • The Cu–Ni nanoalloy phase diagram was calculated by the CALPHAD method. • The Cu–Ni nanoparticles (NPs) were prepared from metal precursors. • NPs were characterized by various methods. • The experimental methods DLS, HRTEM, SEM, XRD, IR, DSC were applied." @default.
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• W2078921621 date "2014-06-01" @default.
• W2078921621 modified "2023-10-07" @default.
• W2078921621 title "Cu–Ni nanoalloy phase diagram – Prediction and experiment" @default.
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• W2078921621 doi "https://doi.org/10.1016/j.calphad.2013.11.004" @default.
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