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• W2078943150 abstract "Carbon and nitrogen K-shell excitation and dissociation of condensed formamide at 96 K were studied by near edge X-ray absorption fine structure (NEXAFS) recorded by total electron yield (TEY), total ion yield (TIY) and photon-stimulated desorption (PSD) yield of H+ measurements. It was found that electronic transitions from the C 1s or the N 1s to the σ∗ (CH and/or NH) enhanced ion yields of H+ from the CH and/or NH functional groups. This selective dissociation indicates that the corresponding unoccupied molecular orbital has an antibonding character of the CH and/or NH. To investigate the molecular orientation of condensed formamide, incidence-angle-dependent TEY-NEXAFS spectra were measured. The CNO plane of the adsorbed formamide molecule is determined to be tilted away from the surface by an averaged angle of about 42°." @default.
• W2078943150 created "2016-06-24" @default.
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• W2078943150 date "2001-01-01" @default.
• W2078943150 modified "2023-09-26" @default.
• W2078943150 title "Inner shell excitation and dissociation of condensed formamide" @default.
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• W2078943150 doi "https://doi.org/10.1016/s0169-4332(00)00671-1" @default.
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