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- W2078943487 abstract "Various isoflavones were separated on an uncoated fused-silica capillary electrophoresis (CE) column (110 cm × 75 μm I.D.) using 25 mM ammonium acetate buffer and UV and electrospray ionization mass spectrometric (ESI-MS) detection. CE-ESI-MS with negative-ion electrospray ionization has been shown to be a suitable technique for the determination of this type of natural compound. The modest sample loading of the CE technique can be circumvented by coupling it with MS; in addition, the mass-resolving capability and high sensitivity of MS for structural analysis of mixtures can thus be exploited. Furthermore, ESI-MS allows one not only to determine the molecular mass of isoflavones, but also the presence of various functional groups according to observed losses from the [M - H]− ion during collision-induced dissociation by adjusting some MS parameters." @default.
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- W2078943487 date "1995-07-01" @default.
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- W2078943487 title "Determination of isoflavones using capillary electrophoresis in combination with electrospray mass spectrometry" @default.
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- W2078943487 doi "https://doi.org/10.1016/0021-9673(95)00343-l" @default.
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