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- W2078960754 abstract "The interaction between 1,1,2,2-tetraphenylethane and di-n-butylzirconium diethoxide (1:2 ratio) in THF at 25 °C does not occur in the dark but does proceed under ambient light (>300 nm). Supplemental illumination, especially in the presence of catalytic amounts of iron salts (e.g., Fe(acac)3 or FeCl3), can lead quantitatively to Ph2CH−Zr(OEt)2−CHPh2, which with H2O (D2O) provides Ph2CH2 (Ph2CHD), and to 1,8-octanediol with some 1-butanol from cleavage of THF." @default.
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- W2078960754 date "2007-01-09" @default.
- W2078960754 modified "2023-10-12" @default.
- W2078960754 title "Illuminating the Unexpected Benzylic Carbon−Carbon Bond Cleavage of Arylated Ethanes with Di-<i>n</i>-Butylzirconium Diethoxide by Illumination: Transfer Epizirconation as Exclusively a Photochemical Process<sup>1</sup>" @default.
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- W2078960754 doi "https://doi.org/10.1021/om061009y" @default.
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