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- W2078974987 abstract "The spectra of the diketone compounds biacetyl, acetylacetone, acetonylacetone, 1,2-cyclohexanedione, and 1,4-cyclohexanedione have been investigated by the technique of low-energy variable-angle electron energy-loss spectroscopy. With this method low-lying, spin-forbidden transitions have been observed. The energy difference between the lowest spin-allowed and spin-forbidden n→π* excitations in the acyclic diketones is found to be 0.35 eV, on average, which is nearly the same as that of comparable acyclic monoketone compounds; in 1,2-cyclohexanedione, however, this energy difference is 0.84 eV, more than twice as large. This discrepancy in the magnitude of the n→π* singlet–triplet splittings may be attributed to differing amounts of overlap between the initial and final orbitals." @default.
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- W2078974987 date "1987-06-15" @default.
- W2078974987 modified "2023-09-24" @default.
- W2078974987 title "Electron‐impact spectroscopy of various diketone compounds" @default.
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- W2078974987 doi "https://doi.org/10.1063/1.452418" @default.
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