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• W2078977575 abstract "New series of platinum complexes of cyclopropenylidenes of the types of PtX2(CP)2 and trans-PtX(PBu3)2(CP) have been synthesized, where CP is di-t-butylcyclopropenylidene (BCP) or bis(diisopropylamino)cyclopropenylidene (ACP). The 13C-NMR chemical shifts, and 13C−195Pt coupling constants (1JPtC) for the complexes are discussed in comparison with those values derived from closely related series of compounds, trans-PtCl(PR3)2L; L  CH3, C6H5 and CCBu-t. An excellent linear relationship through the origin was obtained between 1JPtC and the formal ‘s’ % character of the carbon directly bonded to Pt for the series trans-PtCl(PR3)2L in which the PtC bond is regarded as a pure σ-linkage, whereas 1JPtC deviates largely from this relationship when pπdπ bonding interaction possibly exists in the PtC bond. The NMR data suggest the strong nmr trans-influence of the cyclopropenylidenes and that in the PtCP bond the σ-interaction is appreciable but the π-interaction is negligible." @default.
• W2078977575 created "2016-06-24" @default.
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• W2078977575 date "1988-11-01" @default.
• W2078977575 modified "2023-10-18" @default.
• W2078977575 title "Syntheses, spectroscopic characterization and electronic structure of cyclopropenylidene ligated platinum complexes" @default.
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• W2078977575 doi "https://doi.org/10.1002/poc.610010604" @default.
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