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- W2078985853 abstract "The binding of isolated oxygen atoms to small tantalum clusters is investigated using vibrational spectroscopy. Infrared spectra of TanO0,1,2+ (n = 6−11) are reported in the range of 90−1100 cm−1, comprising both the internal cluster modes and the adatom’s vibrations. The vibrational spectra are compared to the results of DFT calculations for n = 6−8, which show that the oxygen atoms bind preferentially as 2-fold bridging adatoms. Addition of one or two O atoms induces only minor distortions of the underlying metal cluster core." @default.
- W2078985853 created "2016-06-24" @default.
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- W2078985853 date "2010-05-26" @default.
- W2078985853 modified "2023-09-24" @default.
- W2078985853 title "Infrared Spectroscopy and Binding Geometries of Oxygen Atoms Bound to Cationic Tantalum Clusters" @default.
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- W2078985853 doi "https://doi.org/10.1021/jp102084n" @default.
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