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- W2078991749 abstract "Abstract We have developed a convenient synthetic approach to highly reactive N ‐(arylsulfonyl)trichloro‐ and ‐trifluoroacetimidoyl chlorides 2 by reacting the corresponding N ‐acylsulfonamides with PCl 5 . The interaction of the imidoyl chlorides with phosphites proceeds through different pathways depending on the substituents in the reagents, and leads to N ‐arylsulfonyl‐ N ‐trichlorovinylphosphoramidates 4 , 1‐arylsulfonylamino‐1‐chlorotrifluoroethylphosphonate 5 , C , N ‐bis(phosphorylated) N ‐dihalovinylsulfonamides 8 and α‐(arylsulfonylamino)trifluoroethylidenebis(phosphonates) 10 . A rare example of an aza‐Perkow reaction involving a trifluoromethyl group was discovered. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003)" @default.
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- W2078991749 date "2003-10-16" @default.
- W2078991749 modified "2023-09-25" @default.
- W2078991749 title "N-(Arylsulfonyl)trihaloacetimidoyl Chlorides and Their Reactions with Phosphites" @default.
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- W2078991749 doi "https://doi.org/10.1002/ejoc.200300275" @default.
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