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- W2078993345 abstract "The dichloride complex Cp∗(Am)WCl 2 ( 1 , Am = [(iPrN) 2 CMe] − ) reacted with the primary silanes PhSiH 3 , ( p -tolyl)SiH 3 , (3,5-xylyl)SiH 3 , and (C 6 F 5 )SiH 3 to produce the W(VI) (silyl)trihydrides Cp∗(Am)W(H) 3 (SiHPhCl) ( 2 ), Cp∗(Am)W(H) 3 (SiHTolylCl) ( 3 ), Cp∗(Am)W(H) 3 (SiHXylylCl) ( 4 ), and Cp∗(Am)W(H) 3 [SiH(C 6 F 5 )Cl] ( 5 ). In an analogous manner, 1 reacted with PhSiH 2 Cl to give Cp∗(Am)W(H) 3 (SiPhCl 2 ) ( 6 ). Complex 6 can alternatively be quantitatively produced from the reaction of 2 with Ph 3 CCl. NMR spectroscopic studies and X-ray crystallography reveal an interligand H⋯Si interaction between one W–H and the chlorosilyl group, which is further supported by DFT calculations." @default.
- W2078993345 created "2016-06-24" @default.
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- W2078993345 date "2011-03-01" @default.
- W2078993345 modified "2023-09-27" @default.
- W2078993345 title "Interligand H⋯Si interactions in tungsten silyl trihydride complexes" @default.
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- W2078993345 doi "https://doi.org/10.1016/j.jorganchem.2010.11.046" @default.
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