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- W2078994885 abstract "Neutral nickel(II) complexes [[R–NP]NiPh(PPh3)](1, R = H; 2, R = CH3) bearing P,N-chelate ligands ([H–NP] = (2-diphenylphosphanyl)benzenamine L1; [CH3–NP] = (2-diphenylphosphanyl) N-methylbenzenamine L2) have been synthesized and characterized. The molecular structure of complex 1 has been confirmed by single-crystal X-ray analyses. Afteractivation with methylaluminoxane (MAO), catalytic precursors 1 and 2 could polymerize norbornene to afford addition-type polynorbornene (PNB) with very high activities (4.43 × 107 g-PNB mol–1-Ni h–1), high molecular weight Mw (3.07 × 106 g mol–1) and moderate molecular weight distribution Mw/Mn. Catalytic activities, polymer yield, Mw and Mw/Mn of PNB have been investigated under various reaction conditions. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005)" @default.
- W2078994885 created "2016-06-24" @default.
- W2078994885 creator A5025547055 @default.
- W2078994885 creator A5081370621 @default.
- W2078994885 date "2005-04-28" @default.
- W2078994885 modified "2023-09-28" @default.
- W2078994885 title "Highly Active Neutral Nickel( <scp>II</scp> ) Complexes Bearing P,N‐Chelate Ligands: Synthesis, Characterization and Their Application to Addition Polymerization of Norbornene" @default.
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- W2078994885 doi "https://doi.org/10.1002/ejic.200400856" @default.
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