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• W2078997588 endingPage "2051" @default.
• W2078997588 startingPage "2049" @default.
• W2078997588 abstract "A 2 × 2 layer-buckled manganese oxide, K0.66Mn2O4·0.28H2O (I), has been synthesized under high pressure and retained at ambient pressure; it is metastable and will finally transform to a 2 × 1 layer-buckled K0.99Mn3O6·1.25H2O (II) in 1 year. Both crystal structures were determined by single-crystal X-ray diffraction. On the basis of these buckled layers, which are a result of ordering of Mn3+/Mn4+ in separate rows and cooperative Jahn−Teller distortion of Mn3+O6 octahedra, a mechanism of structure transformation from birnessite to tunnel structures was proposed." @default.
• W2078997588 created "2016-06-24" @default.
• W2078997588 creator A5010642871 @default.
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• W2078997588 creator A5050177595 @default.
• W2078997588 creator A5054560949 @default.
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• W2078997588 date "2011-01-26" @default.
• W2078997588 modified "2023-10-09" @default.
• W2078997588 title "Buckled Layers in K_0.66Mn₂O₄·0.28H₂O and K_0.99Mn₃O₆·1.25H₂O Synthesized at High Pressure: Implication for the Mechanism of Layer-to-Tunnel Transformation in Manganese Oxides" @default.
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• W2078997588 doi "https://doi.org/10.1021/ic102282v" @default.
• W2078997588 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/21268604" @default.
• W2078997588 hasPublicationYear "2011" @default.
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