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- W2079006006 abstract "The reaction of [Au(C6F5)2(acac)](acac = acetylacetonate) with (Ph2P)3CH led to [Au(C6F5)2-{(Ph2P)2CPPh2}]1, which reacts further with [AuX(tht)](X = Cl or C6F5, tht = tetrahydrothiophene), [Au(tht)2]ClO4 or AgClO4 to give dinuclear [(F5C6)2Au{(Ph2P)2CPPh2}AuX] or trinuclear complexes [{Au(C6F5)2[(Ph2P)2CPPh2]}2M](M = Au or Ag). Complex 1 reacted with gold(III) complexes to give dinuclear [(F5C6)2Au{( Ph2P)2CPPh2}Au(C6F5)2X](X = Cl or C6F5) or trinuclear complexes [{Au-(C6F5)2[(Ph2P)2CPPh2]}2Au(C6F5)2]. Complex 1 is protonated by reaction with HBF4. The structures of complex 1 and [(F5C6)2Au{(Ph2P)2CPPh2}AuCl] have been established by X-ray crystallography, confirming in the latter that the gold(I) centre is co-ordinated to the free phosphorus instead of the methanide C." @default.
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- W2079006006 title "Tris(diphenylphosphino)methanide gold(<scp>III</scp>) complexes. Crystal structures of [Au(C<sub>6</sub>F<sub>5</sub>)<sub>2</sub>{(Ph<sub>2</sub>P)<sub>2</sub>CPPh<sub>2</sub>}] and [(F<sub>5</sub>C<sub>6</sub>)<sub>2</sub>Au{(Ph<sub>2</sub>P)<sub>2</sub>CPPh<sub>2</sub>}AuCl]" @default.
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- W2079006006 doi "https://doi.org/10.1039/dt9940003487" @default.
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