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- W2079011628 abstract "Abstract Treatment of 3‐alkoxycarbonyl‐4‐acyl‐ or 3,4‐dialkoxycarbonyl‐substituted isoxazolidines with a mild base, such as tetrabutylammonium fluoride, affords β‐enaminones and/or 3‐methylamino‐2(5 H )‐furanones according to the nature of the substituents at C 4 and C 5 . Two alternative mechanisms (lactonization and retro‐aldolization) have been rationalized by DFT quantum chemical methods. Any realistic theoretical modeling requires the explicit inclusion of countercation and solvent effects." @default.
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- W2079011628 date "2010-09-10" @default.
- W2079011628 modified "2023-10-17" @default.
- W2079011628 title "Competitive Formation of β‐Enaminones and 3‐Amino‐2(5<i>H</i>)‐furanones from the Isoxazolidine System: A Combined Synthetic and Quantum Chemical Study" @default.
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