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- W2079015551 abstract "The effect of α- or β-copper phthalocyanine (CuPc) as a nucleating agent during the crystallization of trans-1,4-polyisoprene (TPI) was evaluated using polarized optical microscopy (POM), differential scanning calorimetry (DSC) and wide angle X-ray diffraction (WAXD). Pure TPI crystallizes into either a high-melting crystal form (HMF) or a low-melting crystal form (LMF), depending on the cooling condition of the melt. The HMF melts at ∼60 °C and LMF typically melts at ∼50 °C. Observation by POM showed that the LMF is generated at the interface between TPI and either α- or β-CuPc, selectively, when crystallized at 38 °C. In DSC measurements, the TPI composites containing α- or β-CuPc showed a higher crystallization temperature than that of pure TPI during the melt cooling process. Such results provided evidence that the α- or β-CuPc acted as a nucleating agent for TPI. The data obtained from WAXD proved that the HMF was generated mainly when pure TPI was cooled from the melt at a rate of 5 °C min−1, while the LMF was generated predominantly when the TPI/α- or β-CuPc composites were crystallized under the same cooling conditions as those used for pure TPI. These results led to the conclusion that α- and β-CuPc acted as phase selective nucleating agents for LMF-TPI. Effect of α- or β-Copper phthalocyanine (CuPc) as a nucleating agent through crystallization of trans-1,4-polyisoprene (TPI) was evaluated. Observation by polarized optical microscopy showed that the low-melting crystal form is generated at the interface between TPI and either of α- or β-CuPc selectively when crystallized at 38 °C. In differential scanning calorimetry measurements, TPI composites containing α- or β-CuPc showed higher crystallization temperature than that of pure TPI during the cooling process from the melt." @default.
- W2079015551 created "2016-06-24" @default.
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- W2079015551 date "2013-02-06" @default.
- W2079015551 modified "2023-09-27" @default.
- W2079015551 title "Nucleation and polymorphism of trans-1,4-polyisoprene containing copper phthalocyanine" @default.
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- W2079015551 doi "https://doi.org/10.1038/pj.2013.3" @default.
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