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- W2079018529 abstract "A comparative study of various oxidizing agents for oxidation of thallium (I) to thallium (III) has been made. Aqua regia oxidation gives slightly low results and requires careful treatment. The proposed bromine oxidation not only gives complete oxidation but also offers many other advantages of accuracy, simplicity, and rapidity. The effective oxidation is made possible due to the presence of excess bromine and stabilization of thallic ion by complex formation. An oxidation-resistant dye (PAR or PAN) should be used as indicator in the EDTA titration of thallium (III). Since the thallium (III)-EDTA complex is easily reduced, thallium and other metals may be titrated stepwise in the same solution. The proposed method has been successfully applied to the analysis of lead-thallium alloys." @default.
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- W2079018529 date "1964-09-01" @default.
- W2079018529 modified "2023-10-08" @default.
- W2079018529 title "Bromine oxidation in a highly selective EDTA titration of thallium" @default.
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- W2079018529 doi "https://doi.org/10.1016/0026-265x(64)90110-9" @default.
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