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• W2079021498 abstract "The work introduces a synthesis of novel amphiphilic p-tert-butylphenol derivatives with the polyethyleneoxide and biodegradable ionogenic polyethylenecarbonate moieties. The dependence of their aggregation behaviour on the lengths of polyethyleneoxide and polyethylenecarbonate chains indicates the impact of the hydrophilic moieties and ionogenic end-groups in the aggregation behaviour of the amphiphiles. The micelles of the amphiphiles are negatively charged, although neither pH nor counter ions (exemplified by Gd(III) ions) affects the values of their critical micelle concentrations. The presence of the ionogenic end-groups is the main reason of the pH and concentration dependent extraction of Gd(III) ions from the neutral (pH 6.2-7.2) aqueous solutions of the amphiphiles through their phase separation at room temperatures. The extraction regularities point on the stoichiometric binding of the amphiphilic molecules with Gd(III) ions as the main reason of the phase separation in their aqueous solutions. Nevertheless the micellization of the amphiphiles is responsible for the peculiar concentration effect on the extraction of Gd(III) ions from the aqueous solutions." @default.
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• W2079021498 date "2015-09-01" @default.
• W2079021498 modified "2023-09-27" @default.
• W2079021498 title "Synthesis and aggregation properties of new biodegradable amphiphilic derivatives of p-tert-butylphenol for green separation of Gd(III) ions" @default.
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• W2079021498 doi "https://doi.org/10.1016/j.colsurfa.2014.08.015" @default.
• W2079021498 hasPublicationYear "2015" @default.
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