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- W2079038159 abstract "The title compound, (η5-C5H5)2Mo2(CO)4 (μ-EtCCEt) in its crystalline form, has a molecular structure that lacks symmetry. Two (ηs-C5H5)Mo groups are connected by an MoMo bond 2.977(1) Å in length with the usual sort of crosswise acetylene bridge. There are two terminal CO groups on Mo(1) and one on Mo(2). The fourth CO group is in a semi-bridging posture with Mo(2)—C = 1.936(6) and Mo(1)—C = 2.826(6). The 13CO NMR spectrum at −126°C has six lines, indicative of the presence of two isomers, in each of which two CO's are either statically or dynamically equivalent. Complex changes occur in the spectrum as the temperature is increased so that at −40°C there is only a single line. A detailed interpretation of these spectra is not yet available." @default.
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- W2079038159 date "1976-11-01" @default.
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- W2079038159 title "Unexpectedly complex structure and dynamic behavior of bis [(η5-cyclopentadienyl)dicarbonyl molybdenum ]-μ-pent-3-yne (MoMo)" @default.
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- W2079038159 doi "https://doi.org/10.1016/s0022-328x(00)80779-2" @default.
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