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- W2079040461 abstract "Abstract The effect of a non-polar solvent on the vibrational spectrum of the linear triatomic hydrogen-bonded complex AH⋯B has been analyzed by means of perturbation theory. The anharmonicity and coupling of complex vibrations were taken into account. The calculations have been performed for the complexes CH 3 CN⋯HCl and HCN⋯HF. The changes in vibrational frequencies, anharmonicity constants and electro-optical parameters have been estimated. The results obtained are in qualitative agreement with the experimentally observed changes of νAH band moments. The conclusion have been drawn that additional broadening of the νAH band, caused by fluctuations in its shift value, should be suggested to explain the increase of the second moment of the band in solution." @default.
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- W2079040461 date "1992-07-01" @default.
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- W2079040461 title "Solvent effect on the vibrational spectrum of a hydrogen-bonded complex" @default.
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- W2079040461 doi "https://doi.org/10.1016/0022-2860(92)85048-l" @default.
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