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• W2079042802 startingPage "6164" @default.
• W2079042802 abstract "Densely-packed alkyl monolayers similar to those previously reported by Linford et al.1,2 are formed by the reaction of 1-alkenes with hydrogen-terminated surfaces of both Si(111) and Si(100). The thermal behavior of these monolayers in vacuum has been studied using high-resolution electron energy loss spectroscopy. Both on Si(111) and on Si(100), the monolayers are found to be stable up to about 615 K. Desorption is signaled by a decrease in the intensity of C−H modes, accompanied by the appearance of Si−H modes, which suggests that desorption occurs through β-hydride elimination reactions. Upon further annealing to 785 K, C−H and Si−H modes essentially disappear, and a peak appears at 780 cm-1, which is attributed to a SiC vibrational mode. This behavior indicates that decomposition of the monolayers has taken place." @default.
• W2079042802 created "2016-06-24" @default.
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• W2079042802 date "1997-11-01" @default.
• W2079042802 modified "2023-09-25" @default.
• W2079042802 title "Thermal Behavior of Alkyl Monolayers on Silicon Surfaces" @default.
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• W2079042802 doi "https://doi.org/10.1021/la9705928" @default.
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