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• W2079047557 startingPage "106" @default.
• W2079047557 abstract "Mesoporous LiFePO4/C microspheres consisting of LiFePO4 nanoparticles are successfully fabricated by an eco-friendly hydrothermal approach combined with high-temperature calcinations using cost-effective LiOH and Fe3+ salts as raw materials. In this strategy, pure mesoporous LiFePO4 microspheres, which are composed of LiFePO4 nanoparticles, were uniformly coated with carbon (∼1.5 nm). Benefiting from this unique architecture, these mesoporous LiFePO4/C microspheres can be closely packed, having high tap density. The initial discharge capacity of LiFePO4/C microspheres as positive-electrode materials for lithium-ion batteries could reach 165.3 mAh/g at 0.1 C rate, which is notably close to the theoretical capacity of LiFePO4 due to the large BET surface area, which provides for a large electrochemically available surface for the active material and electrolyte. The material also exhibits high rate capability (∼100 mAh/g at 8 C) and good cycling stability (capacity retention of 92.2% after 400 cycles at 8 C rate)." @default.
• W2079047557 created "2016-06-24" @default.
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• W2079047557 date "2014-12-01" @default.
• W2079047557 modified "2023-10-07" @default.
• W2079047557 title "Mesoporous composite of LiFePO4 and carbon microspheres as positive-electrode materials for lithium-ion batteries" @default.
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• W2079047557 doi "https://doi.org/10.1016/j.partic.2014.03.008" @default.
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