FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2079067759> ?p ?o ?g. }

• W2079067759 endingPage "7580" @default.
• W2079067759 startingPage "7571" @default.
• W2079067759 abstract "Treatment of per- or polyfluoroalkylated vinyl iodides 5 with 2 equiv. of n-BuLi in THF produced the corresponding lithium acetylides in situ, which were transformed into zinc acetylides by the addition of ZnCl2·TMEDA complex into the reaction mixture. The in situ generated zinc acetylides were exposed to the cross-coupling conditions such as ArI/cat. Pd(PPh3)4, reflux, 6–12 h, giving rise to the desired per- or polyfluoroalkylated acetylenes in high yields. In the case of trifluoromethylated acetylene, commercially available 2-bromo-3,3,3-trifluoropropene 6 could also be used instead of 5 as the starting material. In the acetylenes having a fluoroalkyl group and an aliphatic side chain, vinyl iodides 7, prepared by radical addition of perfluoroalkyl iodide to terminal acetylenes, were treated with t-BuOK at room temperature or at the reflux temperature of benzene, affording the desired compounds in good yields." @default.
• W2079067759 created "2016-06-24" @default.
• W2079067759 creator A5008090502 @default.
• W2079067759 creator A5030215085 @default.
• W2079067759 creator A5035403259 @default.
• W2079067759 creator A5039076567 @default.
• W2079067759 creator A5047469748 @default.
• W2079067759 creator A5061320155 @default.
• W2079067759 creator A5066068998 @default.
• W2079067759 date "2003-09-01" @default.
• W2079067759 modified "2023-09-30" @default.
• W2079067759 title "Facile syntheses of various per- or polyfluoroalkylated internal acetylene derivatives" @default.
• W2079067759 cites W1964967054 @default.
• W2079067759 cites W1966000633 @default.
• W2079067759 cites W1967420402 @default.
• W2079067759 cites W1970015679 @default.
• W2079067759 cites W1978018439 @default.
• W2079067759 cites W1983130896 @default.
• W2079067759 cites W1983206590 @default.
• W2079067759 cites W1985980974 @default.
• W2079067759 cites W1999103798 @default.
• W2079067759 cites W2001261398 @default.
• W2079067759 cites W2003782942 @default.
• W2079067759 cites W2036854017 @default.
• W2079067759 cites W2039275173 @default.
• W2079067759 cites W2051769797 @default.
• W2079067759 cites W2063478816 @default.
• W2079067759 cites W2070272412 @default.
• W2079067759 cites W2081582050 @default.
• W2079067759 cites W2135945161 @default.
• W2079067759 cites W2142982288 @default.
• W2079067759 cites W2146842035 @default.
• W2079067759 cites W2153731682 @default.
• W2079067759 cites W2165150398 @default.
• W2079067759 cites W2329600105 @default.
• W2079067759 cites W2949143222 @default.
• W2079067759 cites W2949926892 @default.
• W2079067759 cites W2951781304 @default.
• W2079067759 cites W4240136242 @default.
• W2079067759 cites W588545834 @default.
• W2079067759 doi "https://doi.org/10.1016/s0040-4020(03)01199-2" @default.
• W2079067759 hasPublicationYear "2003" @default.
• W2079067759 type Work @default.
• W2079067759 sameAs 2079067759 @default.
• W2079067759 citedByCount "69" @default.
• W2079067759 countsByYear W20790677592012 @default.
• W2079067759 countsByYear W20790677592013 @default.
• W2079067759 countsByYear W20790677592014 @default.
• W2079067759 countsByYear W20790677592015 @default.
• W2079067759 countsByYear W20790677592016 @default.
• W2079067759 countsByYear W20790677592017 @default.
• W2079067759 countsByYear W20790677592018 @default.
• W2079067759 countsByYear W20790677592019 @default.
• W2079067759 countsByYear W20790677592020 @default.
• W2079067759 countsByYear W20790677592021 @default.
• W2079067759 countsByYear W20790677592022 @default.
• W2079067759 crossrefType "journal-article" @default.
• W2079067759 hasAuthorship W2079067759A5008090502 @default.
• W2079067759 hasAuthorship W2079067759A5030215085 @default.
• W2079067759 hasAuthorship W2079067759A5035403259 @default.
• W2079067759 hasAuthorship W2079067759A5039076567 @default.
• W2079067759 hasAuthorship W2079067759A5047469748 @default.
• W2079067759 hasAuthorship W2079067759A5061320155 @default.
• W2079067759 hasAuthorship W2079067759A5066068998 @default.
• W2079067759 hasConcept C134018914 @default.
• W2079067759 hasConcept C147789679 @default.
• W2079067759 hasConcept C155647269 @default.
• W2079067759 hasConcept C17525397 @default.
• W2079067759 hasConcept C178790620 @default.
• W2079067759 hasConcept C185592680 @default.
• W2079067759 hasConcept C188027245 @default.
• W2079067759 hasConcept C2776682256 @default.
• W2079067759 hasConcept C2777517455 @default.
• W2079067759 hasConcept C2777691172 @default.
• W2079067759 hasConcept C2777822432 @default.
• W2079067759 hasConcept C2778541603 @default.
• W2079067759 hasConcept C2778870691 @default.
• W2079067759 hasConcept C2780073701 @default.
• W2079067759 hasConcept C535196362 @default.
• W2079067759 hasConcept C68801617 @default.
• W2079067759 hasConcept C71924100 @default.
• W2079067759 hasConceptScore W2079067759C134018914 @default.
• W2079067759 hasConceptScore W2079067759C147789679 @default.
• W2079067759 hasConceptScore W2079067759C155647269 @default.
• W2079067759 hasConceptScore W2079067759C17525397 @default.
• W2079067759 hasConceptScore W2079067759C178790620 @default.
• W2079067759 hasConceptScore W2079067759C185592680 @default.
• W2079067759 hasConceptScore W2079067759C188027245 @default.
• W2079067759 hasConceptScore W2079067759C2776682256 @default.
• W2079067759 hasConceptScore W2079067759C2777517455 @default.
• W2079067759 hasConceptScore W2079067759C2777691172 @default.
• W2079067759 hasConceptScore W2079067759C2777822432 @default.
• W2079067759 hasConceptScore W2079067759C2778541603 @default.
• W2079067759 hasConceptScore W2079067759C2778870691 @default.
• W2079067759 hasConceptScore W2079067759C2780073701 @default.
• W2079067759 hasConceptScore W2079067759C535196362 @default.
• W2079067759 hasConceptScore W2079067759C68801617 @default.
• W2079067759 hasConceptScore W2079067759C71924100 @default.

• next