FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2079073312> ?p ?o ?g. }

• W2079073312 endingPage "11441" @default.
• W2079073312 startingPage "11434" @default.
• W2079073312 abstract "The synthesis of a series of cyclic pentaoxyphosphoranes containing a sulfonyl group was carried out by the reaction of either P(OCH2CF3)3 or P(OPh)3 with the appropriate diol in an oxidative addition reaction: O2S[(t-Bu)MeC6H2O]2P(OCH2CF3)3 (1), O2S[(t-Bu)MeC6H2O]2P(OPh)3 (2), O2S[(t-Bu)2C6H2O]2P(OCH2CF3)3 (4), and O2S[(t-Bu)2C6H2O]2P(OPh)3 (5). Reaction of 2 with catechol yielded O2S[(t-Bu)MeC6H2O]2P(OPh)(C6H4O2) (3). X-ray studies provided the structures of 1−5, although 4 was badly disordered. The geometries of 2, 3, and 5 are octahedral due to P−O coordination provided by the sulfonyl group, whereas 1 and 4 are trigonal bipyramidal. Solution 31P, 1H, and 19F NMR spectra demonstrate that 1 and 4 exist in isomeric modifications. These are formulated as a pentacoordinate structure, as in the solid state, and a hexacoordinate structure. This represents the first study establishing intramolecular intraconversion between penta- and hexacoordinate isomers of phosphorus. An activation free energy of 17 kcal/mol for the exchange process for 1 and 4 was obtained from variable temperature 1H NMR spectra." @default.
• W2079073312 created "2016-06-24" @default.
• W2079073312 creator A5029834509 @default.
• W2079073312 creator A5075895277 @default.
• W2079073312 creator A5077293086 @default.
• W2079073312 date "1997-11-01" @default.
• W2079073312 modified "2023-09-26" @default.
• W2079073312 title "Isomeric Intraconversion among Penta- and Hexacoordinate Cyclic Oxyphosphoranes via Oxygen Atom Coordination¹^,²" @default.
• W2079073312 cites W1985684677 @default.
• W2079073312 cites W1999584998 @default.
• W2079073312 cites W2001490445 @default.
• W2079073312 cites W2010394903 @default.
• W2079073312 cites W2021125922 @default.
• W2079073312 cites W2029942958 @default.
• W2079073312 cites W2030841140 @default.
• W2079073312 cites W2034728799 @default.
• W2079073312 cites W2041441622 @default.
• W2079073312 cites W2068926348 @default.
• W2079073312 cites W2074310462 @default.
• W2079073312 cites W2082242343 @default.
• W2079073312 cites W2089122382 @default.
• W2079073312 cites W2148066840 @default.
• W2079073312 cites W2166696198 @default.
• W2079073312 cites W2312988062 @default.
• W2079073312 cites W2949916973 @default.
• W2079073312 cites W2951295560 @default.
• W2079073312 cites W2951574389 @default.
• W2079073312 cites W2952188841 @default.
• W2079073312 cites W2953133669 @default.
• W2079073312 cites W2955325980 @default.
• W2079073312 cites W3004473906 @default.
• W2079073312 cites W3137851917 @default.
• W2079073312 cites W4232569651 @default.
• W2079073312 cites W4252312280 @default.
• W2079073312 cites W4256326391 @default.
• W2079073312 doi "https://doi.org/10.1021/ja9722988" @default.
• W2079073312 hasPublicationYear "1997" @default.
• W2079073312 type Work @default.
• W2079073312 sameAs 2079073312 @default.
• W2079073312 citedByCount "40" @default.
• W2079073312 countsByYear W20790733122015 @default.
• W2079073312 countsByYear W20790733122018 @default.
• W2079073312 countsByYear W20790733122021 @default.
• W2079073312 countsByYear W20790733122022 @default.
• W2079073312 crossrefType "journal-article" @default.
• W2079073312 hasAuthorship W2079073312A5029834509 @default.
• W2079073312 hasAuthorship W2079073312A5075895277 @default.
• W2079073312 hasAuthorship W2079073312A5077293086 @default.
• W2079073312 hasConcept C111592845 @default.
• W2079073312 hasConcept C115624301 @default.
• W2079073312 hasConcept C121332964 @default.
• W2079073312 hasConcept C1276947 @default.
• W2079073312 hasConcept C155647269 @default.
• W2079073312 hasConcept C161790260 @default.
• W2079073312 hasConcept C178790620 @default.
• W2079073312 hasConcept C185592680 @default.
• W2079073312 hasConcept C198819137 @default.
• W2079073312 hasConcept C2778615665 @default.
• W2079073312 hasConcept C2780810681 @default.
• W2079073312 hasConcept C4839761 @default.
• W2079073312 hasConcept C544956773 @default.
• W2079073312 hasConcept C66974803 @default.
• W2079073312 hasConcept C67787023 @default.
• W2079073312 hasConcept C71240020 @default.
• W2079073312 hasConcept C75079739 @default.
• W2079073312 hasConcept C8010536 @default.
• W2079073312 hasConcept C94882840 @default.
• W2079073312 hasConceptScore W2079073312C111592845 @default.
• W2079073312 hasConceptScore W2079073312C115624301 @default.
• W2079073312 hasConceptScore W2079073312C121332964 @default.
• W2079073312 hasConceptScore W2079073312C1276947 @default.
• W2079073312 hasConceptScore W2079073312C155647269 @default.
• W2079073312 hasConceptScore W2079073312C161790260 @default.
• W2079073312 hasConceptScore W2079073312C178790620 @default.
• W2079073312 hasConceptScore W2079073312C185592680 @default.
• W2079073312 hasConceptScore W2079073312C198819137 @default.
• W2079073312 hasConceptScore W2079073312C2778615665 @default.
• W2079073312 hasConceptScore W2079073312C2780810681 @default.
• W2079073312 hasConceptScore W2079073312C4839761 @default.
• W2079073312 hasConceptScore W2079073312C544956773 @default.
• W2079073312 hasConceptScore W2079073312C66974803 @default.
• W2079073312 hasConceptScore W2079073312C67787023 @default.
• W2079073312 hasConceptScore W2079073312C71240020 @default.
• W2079073312 hasConceptScore W2079073312C75079739 @default.
• W2079073312 hasConceptScore W2079073312C8010536 @default.
• W2079073312 hasConceptScore W2079073312C94882840 @default.
• W2079073312 hasIssue "47" @default.
• W2079073312 hasLocation W20790733121 @default.
• W2079073312 hasOpenAccess W2079073312 @default.
• W2079073312 hasPrimaryLocation W20790733121 @default.
• W2079073312 hasRelatedWork W2027555036 @default.
• W2079073312 hasRelatedWork W2068798970 @default.
• W2079073312 hasRelatedWork W2076201064 @default.
• W2079073312 hasRelatedWork W2079073312 @default.
• W2079073312 hasRelatedWork W2094345935 @default.
• W2079073312 hasRelatedWork W2131520832 @default.
• W2079073312 hasRelatedWork W2378159631 @default.
• W2079073312 hasRelatedWork W2378479697 @default.

• next