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- W2079079662 abstract "The coordination of flavins to Lewis-acidic zinc(II)cyclen complexes, as a mimic for a metalloprotein binding site, changes their redox properties significantly. The coordination facilitates the electrochemical reduction of the flavin and stabilizes the flavinhydroquinone redox stage, so that a 600 mV more positive potential is necessary for reoxidation. Binding of flavin to the receptor molecule is not restricted to nonpolar solvents and works in methanol. Here, interception of the ECE mechanism of reduction is possible leading to a stabilization of the flavosemiquinone radical anion redox stage, which was proved by its characteristic UV absorption in spectroelectrochemistry. Although it has not yet been observed in flavoproteins, this study shows that flavin binding by coordination to a metal binding site is suitable for cofactor binding and modulation of its redox properties as well as other intermolecular interactions." @default.
- W2079079662 created "2016-06-24" @default.
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- W2079079662 date "2001-06-01" @default.
- W2079079662 modified "2023-10-10" @default.
- W2079079662 title "A Model System for Flavoenzyme Activity − Binding of Flavin and Modulation of Its Redox Potentials through Coordination to a Lewis-Acidic Azamacrocyclic Zinc(II) Complex" @default.
- W2079079662 cites W19312761 @default.
- W2079079662 cites W1963652442 @default.
- W2079079662 cites W1968255170 @default.
- W2079079662 cites W1969036390 @default.
- W2079079662 cites W1971826572 @default.
- W2079079662 cites W1974814614 @default.
- W2079079662 cites W1977326717 @default.
- W2079079662 cites W1981625343 @default.
- W2079079662 cites W1984679154 @default.
- W2079079662 cites W1984689116 @default.
- W2079079662 cites W1984798563 @default.
- W2079079662 cites W1989160305 @default.
- W2079079662 cites W1989535139 @default.
- W2079079662 cites W1993165015 @default.
- W2079079662 cites W1996924326 @default.
- W2079079662 cites W1999446752 @default.
- W2079079662 cites W1999922097 @default.
- W2079079662 cites W2000991875 @default.
- W2079079662 cites W2002372650 @default.
- W2079079662 cites W2002714756 @default.
- W2079079662 cites W2006217691 @default.
- W2079079662 cites W2007305326 @default.
- W2079079662 cites W2007677502 @default.
- W2079079662 cites W2008058247 @default.
- W2079079662 cites W2011053903 @default.
- W2079079662 cites W2012416108 @default.
- W2079079662 cites W2013648634 @default.
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- W2079079662 cites W2017842486 @default.
- W2079079662 cites W2018612109 @default.
- W2079079662 cites W2021342542 @default.
- W2079079662 cites W2022565210 @default.
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- W2079079662 cites W2028793795 @default.
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- W2079079662 cites W2029784132 @default.
- W2079079662 cites W2031686256 @default.
- W2079079662 cites W2037525686 @default.
- W2079079662 cites W2038104772 @default.
- W2079079662 cites W2038261205 @default.
- W2079079662 cites W2040692262 @default.
- W2079079662 cites W2046643394 @default.
- W2079079662 cites W2048505152 @default.
- W2079079662 cites W2050395859 @default.
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- W2079079662 cites W2062371381 @default.
- W2079079662 cites W2068646212 @default.
- W2079079662 cites W2071508136 @default.
- W2079079662 cites W2074315963 @default.
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- W2079079662 cites W2090669633 @default.
- W2079079662 cites W2095162427 @default.
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- W2079079662 cites W62771670 @default.
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- W2079079662 doi "https://doi.org/10.1002/1099-0690(200106)2001:12<2297::aid-ejoc2297>3.0.co;2-r" @default.
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