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- W2079082922 abstract "Resonance Raman microscopy was used to study the resonance Raman scattering of the diacid (diprotonated form) of free-base porphyrin (21H,23H–porphine) in a crystal powder and KBr pellets. Intensive lines in the spectral range between 100 ÷ 1000 cm− 1 have been detected and assigned as spectral manifestation of out-of-plane modes. The Raman spectra were simulated by means of DFT methods and compared with the experimental data. It is evident from experimental and theoretical results that the activation of out-of-plane modes arises from saddle distortion of the porphyrin macrocycle upon formation of its diprotonated form." @default.
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- W2079082922 date "1978-01-01" @default.
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- W2079082922 title "Experimental and theoretical investigation of infrared spectra of porphin, its deuterated derivatives and their metal complexes" @default.
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- W2079082922 doi "https://doi.org/10.1016/0022-2860(78)87214-7" @default.
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