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- W2079086270 abstract "Abstract A strategy for the synthesis of α‐alkylated ketones via one‐pot, sequential, catalytic hydration of alkynes and α‐alkylation with alcohols was proposed and successfully accomplished. In the presence of chloro[1,3‐bis(2,6‐diisopropylphenyl)imidazol‐2‐ylidene]gold(I) ([(IPr)AuCl])/silver triflate (AgOTf) and water, a series of alkynes are first hydrated to give the corresponding methyl ketones, which in turn are α‐alkylated by adding pentamethylcyclopentadienyliridium(III) chloride ([Cp*IrCl 2 ] 2 )/KO t Bu and alcohols to the reaction mixture. Notably, this reaction is highly attractive because of easily available starting materials, high atom efficiency, good to excellent yields, and minimal consumption of chemicals and energy. The present research will also facilitate the development of one‐pot, sequential, catalytic reactions based on “hydrogen autotransfer” (or “hydrogen‐borrowing”) processes." @default.
- W2079086270 created "2016-06-24" @default.
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- W2079086270 date "2014-06-12" @default.
- W2079086270 modified "2023-10-18" @default.
- W2079086270 title "One-Pot Sequential Catalytic Hydration of Alkynes and α<i>-</i>Alkylation with Alcohols for the Synthesis of α-Alkylated Ketones" @default.
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- W2079086270 doi "https://doi.org/10.1002/ajoc.201402055" @default.
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