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- W2079087122 abstract "Irradiation of W(CO)6 in CCl4 generates an ‘active species’ which has the ability to polymerise alkynes and strained cyclic olefins via a metathesis pathway. The precipitate formed after 2 h of irradiation is active for polymerisation. The involvement of metal carbene in the polymerisation of norbornene was proved by in situ 1H-NMR study and by the end-capping reaction. IR studies showed the presence of carbonyl and chlorine ligands around the tungsten centre." @default.
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- W2079087122 date "2000-04-01" @default.
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- W2079087122 title "Studies on the nature of active species in W(CO)6/CCl4/hν system as applied to metathesis polymerisation reactions" @default.
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- W2079087122 doi "https://doi.org/10.1016/s0022-328x(00)00015-2" @default.
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