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• W2079104039 startingPage "1672" @default.
• W2079104039 abstract "S-(1-Oxido-2-pyridinyl)-1,1,3,3-tetramethylthiouronium hexafluorophosphate (HOTT) facilitates the first examples of efficient radical cyclisation with (hetero)aromatic substitution via Barton ester intermediates. Cyclopropyl and alkyl radicals allow access to five, six and seven-membered alicyclic-ring fused heterocycles with and without an additional fused cyclopropane, including the skeleton of the anti-cancer agent, cyclopropamitosene, expanded, and diazole analogues. Radical initiators are not required for cyclisation from carboxylic acid precursors." @default.
• W2079104039 created "2016-06-24" @default.
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• W2079104039 date "2013-01-01" @default.
• W2079104039 modified "2023-10-01" @default.
• W2079104039 title "Barton esters for initiator-free radical cyclisation with heteroaromatic substitution" @default.
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• W2079104039 doi "https://doi.org/10.1039/c3ob27313j" @default.
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