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• W2079106537 startingPage "8159" @default.
• W2079106537 abstract "Laser ablated chromium, molybdenum, and tungsten atoms react with germane during condensation in excess noble gases. The chromium reaction stopped at the germyl metal hydride, molybdenum gave some hydride but mostly germylidyne, and tungsten reacted spontaneously to give only the germylidyne species. These molecules were identified by isotopic shifts, density-functional theory product energy and frequency calculations, and comparison to the analogous methane and silane reaction products. Effective bond orders for the HGe[triple bond]MoH3 and HGe[triple bond]WH3 molecules are 2.82 and 2.87 using the B3LYP density functional, and are slightly lower than their silicon and carbon analogues. Our calculated Ge[triple bond]M triple bond lengths for these simple trihydride complexes are 0.05 to 0.10 A shorter than those measured for larger group 6 organometallic complexes." @default.
• W2079106537 created "2016-06-24" @default.
• W2079106537 creator A5029634322 @default.
• W2079106537 creator A5084138890 @default.
• W2079106537 date "2008-08-12" @default.
• W2079106537 modified "2023-09-27" @default.
• W2079106537 title "Infrared Spectra, Structure, and Bonding of the GeH₃—CrH, HGe≡MoH₃, and HGe≡WH₃ Molecules in Solid Neon and Argon" @default.
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• W2079106537 doi "https://doi.org/10.1021/ic800552s" @default.
• W2079106537 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/18698694" @default.
• W2079106537 hasPublicationYear "2008" @default.
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