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• W2079106568 abstract "Some synthetically useful transformations of organosilicon compounds have been developed since the mid 1970s, based on the new concept that the silicon-carbon bonds are activated toward electrophilic cleavage via the formation of penta- and hexa-coordinate species. This review mainly consists of the following aspects: (1) a general concept for the activation of the silicon-carbon bond via penta- and hexa-coordinate species, (2) synthetic application of hexa-coordinate organopentafluorosilicates, and (3) development of the H2O2 oxidation of the silicon-carbon bond and its synthetic applications via the intramolecular hydrosilylation, silicon-tethered intramolecular radical cyclization and Diels-Alder reaction, and some silicon-containing organometallic reagents for nucleophilic hydroxymethylation and hydroxyallylation synthons.(Communicated by Hitosi NOZAKI, M.J.A.)" @default.
• W2079106568 created "2016-06-24" @default.
• W2079106568 creator A5033239179 @default.
• W2079106568 date "2008-01-01" @default.
• W2079106568 modified "2023-10-16" @default.
• W2079106568 title "Discovery and synthetic applications of novel silicon-carbon bond cleavage reactions based on the coordination number change of organosilicon compounds" @default.
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• W2079106568 doi "https://doi.org/10.2183/pjab.84.123" @default.
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