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- W2079108534 abstract "Mobility and reactivity of the functionalized fullerenes with pyrrolidine (${mathrm{C}}_{60}mathrm{text{ensuremath{-}}}{mathrm{C}}_{3}{mathrm{NH}}_{7}$) incorporated in single-wall carbon nanotubes were examined by high-resolution transmission electron microscopy. An individual functional group attached to each fullerene cage is unambiguously visualized. This provides a direct evidence for the functionalized structure on a single-molecular basis. A rotational motion of the incorporated molecules tends to occur during the observation and, consequently, each fullerene molecule is likely to stand facing its functionalized group towards the nanotube wall. A fine structure analysis of electron energy-loss spectra for the nitrogen $K$($1s$) edge shows a considerable change in the nitrogen chemical state and suggests a strong tube-fullerene interaction." @default.
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- W2079108534 date "2006-03-02" @default.
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- W2079108534 title "Transmission Electron Microscopy Imaging of Individual Functional Groups of Fullerene Derivatives" @default.
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- W2079108534 doi "https://doi.org/10.1103/physrevlett.96.088304" @default.
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