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• W2079109643 abstract "(+/-)-Deoxydysibetaine 2 and 4-epi-dysibetaine 3 were prepared in a few steps from methyl pyroglutamate through a regioselective Mannich reaction at C-2. Natural (2S,4S)-dysibetaine 1, a sponge metabolite isolated from Dysidea herbacea, and (2S)-2 were synthesized from enantiopure (S)-pyroglutaminol with very high stereoselectivity. The key steps were an original formation of stereogenic quaternary center C-2 and the diastereoselective hydroxylation at C-4." @default.
• W2079109643 created "2016-06-24" @default.
• W2079109643 creator A5064640518 @default.
• W2079109643 creator A5065098401 @default.
• W2079109643 date "2004-09-29" @default.
• W2079109643 modified "2023-10-16" @default.
• W2079109643 title "Diastereoselective Syntheses of Deoxydysibetaine, Dysibetaine, and Its 4-Epimer" @default.
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• W2079109643 doi "https://doi.org/10.1021/jo040216+" @default.
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