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• W2079112305 abstract "The reaction of fac-[M(III)F3(Me3tacn)]⋅x H2O with Gd(NO3)3⋅5H2O affords a series of fluoride-bridged, trigonal bipyramidal {Gd(III)3M(III)2} (M = Cr (1), Fe (2), Ga (3)) complexes without signs of concomitant GdF3 formation, thereby demonstrating the applicability even of labile fluoride-complexes as precursors for 3d-4f systems. Molecular geometry enforces weak exchange interactions, which is rationalized computationally. This, in conjunction with a lightweight ligand sphere, gives rise to large magnetic entropy changes of 38.3 J kg(-1) K(-1) (1) and 33.1 J kg(-1) K(-1) (2) for the field change 7 T→0 T. Interestingly, the entropy change, and the magnetocaloric effect, are smaller in 2 than in 1 despite the larger spin ground state of the former secured by intramolecular Fe-Gd ferromagnetic interactions. This observation underlines the necessity of controlling not only the ground state but also close-lying excited states for successful design of molecular refrigerants." @default.
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• W2079112305 date "2014-02-06" @default.
• W2079112305 modified "2023-10-02" @default.
• W2079112305 title "Fluoride-Bridged {Gd^III₃M^III₂} (M=Cr, Fe, Ga) Molecular Magnetic Refrigerants" @default.
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• W2079112305 doi "https://doi.org/10.1002/anie.201308240" @default.
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