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- W2079113473 abstract "Electrochemical and spectroelectrochemical properties of manganese(III) reconstituted myoglobin (Mn(III)–Mb) have been investigated. No redox wave of Mn(III)–Mb was observed at a highly hydrophilic indium oxide electrode on which rapid direct electron transfer of native myoglobin took place, suggesting the electron transfer reaction of Mn(III)–Mb at an indium oxide electrode is very slow. The rate constant of the chemical reduction of Mn(III)–Mb with dithionite was ca. 20 times smaller than that of native Mb. Using an optically transparent thin layer electrode (OTTLE) cell and Oxazine-170 perchlorate, 5,9-bis(diethylamino)-10-methyl-benzo[a]phenoxazonium perchlorate, as an electron transfer mediator, the redox potential for the Mn(III) ∣ Mn(II)–Mb couple was estimated to be −0.32 V versus Ag ∣ AgCl (sat. KCl) at 25°C." @default.
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- W2079113473 date "1999-01-01" @default.
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- W2079113473 title "Electrochemical and spectroelectrochemical properties of manganese reconstituted myoglobin" @default.
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- W2079113473 doi "https://doi.org/10.1016/s0022-0728(98)00329-5" @default.
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