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• W2079124578 abstract "Abstract A series of unsymmetrically disubstituted diiron complexes [(μ‐pdt){Fe(CO) 2 L 1 }{Fe(CO) 2 L 2 }] [pdt = 1,3‐propanedithiolato; L 1 = PMe 3 , L 2 = PMe 2 Ph, 4 ; PPh 3 , 5 ; PCy 3 , 6 ; P(OEt) 3 , 7 ; L 1 = PMe 2 Ph, L 2 = PPh 3 , 8 ; P(OEt) 3 , 9 ; L 1 = P(OEt) 3 , L 2 = PPh 3 , 10 ; PCy 3 , 11 ] and [(μ‐edt){Fe(CO) 2 PMe 3 }{Fe(CO) 2 PPh 3 }] (edt = 1,2‐ethanedithiolato, 12 ) were prepared by means of stepwise CO displacements of [(μ‐pdt)Fe 2 (CO) 6 ] and [(μ‐edt)Fe 2 (CO) 6 ] by different tertiary phosphane and phosphite ligands. The interconversion of the irondithiacyclohexane ring and the rotation of the [Fe(CO) 2 PR 3 ] subunit were studied using by variable‐temperature 31 P{ 1 H} NMR spectroscopy of 4 , 6 and 12 in solution. The molecular structures of 4 – 6 , 8 – 10 and 12 show that complexes 4 – 6 , 8 , 9 and 12 possess an apical/basal coordination mode and complex 10 has an apical/apical conformation. The X‐ray analyses indicate that the PMe 2 Ph ligand in the apical position of the starting complex [(μ‐pdt){Fe(CO) 3 }{FeCO 2 (PMe 2 Ph)}] rotates to the basal position on conversion to the products 8 and 9 . Cyclic voltammograms of 4 – 11 were studied both under argon and CO. The influences of the phosphane and phosphite ligands on the redox properties of the unsymmetrically disubstituted diiron complexes are discussed. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)" @default.
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• W2079124578 date "2007-07-31" @default.
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• W2079124578 title "Phosphane and Phosphite Unsymmetrically Disubstituted Diiron Complexes Related to the Fe‐Only Hydrogenase Active Site" @default.
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• W2079124578 doi "https://doi.org/10.1002/ejic.200601184" @default.
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