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- W2079131171 abstract "The method previously described 1 This is the second of a series of communications on the influence of substituents on the reactivity of aromatic compounds. For the first communication cf: F. L. J. Sixma, J. Chem. Phys. 19, 1209 (1951). for calculating the influence of the electric field of a substituent (inductive effect) on the energy content of the intermediate complex of substitution reactions in the benzene nucleus, proceeding from the known values of dipole moments, bond lengths and valency angles, is further elaborated. The theory is tested on the experimental results for electrophilic substitution reactions. The agreement between calculated and experimental values for the percentage meta-substitution is very satisfactory for those substituents which show little or no resonance interaction (E-effect) with the pentadienate cation." @default.
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- W2079131171 date "2010-09-02" @default.
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- W2079131171 title "On the theory of aromatic substitution: I. A theoretical treatment of the effect of poles and dipoles on the substitution type" @default.
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- W2079131171 doi "https://doi.org/10.1002/recl.19530720403" @default.
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