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- W2079135054 abstract "Abstract Steric congestion of reaction centers produces late transition states in organic reactions. Intrusion of steric hindrance induces a stronger pressure acceleration. Some relevant examples are given: Menshutkin, Wittig, Michael, Henry reactions, cycloadditions. The pressure parameter is, therefore, of high value in the synthesis of crowded molecules via sterically demanding reactions." @default.
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- W2079135054 date "1993-01-01" @default.
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- W2079135054 title "Kinetic effects of high pressure in congested and strained molecular systems. A useful application of high pressure in organic synthesis" @default.
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