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- W2079138217 abstract "The enzymatic reduction of hydrophobic ketones in cyclodextrin containing media is reported yielding the corresponding alcohols (S)-1-(2-naphthyl)-ethanol, (S)-(E)-4-phenyl-3-en-2-ol and 1,2,3,4-tetrahydro-2-(1-hydroxyethyl)-1-oxonaphthalene in good yield and high enantiomeric excess. The reaction was catalyzed by a carbonyl reductase from Candida parapsilosis, NADH regeneration was carried out using either 2-propanol in a substrate coupled mode or formate dehydrogenase from Candida boidinii and formate as hydrogen donor. In continuous experiments high stability of the enzymes in media containing heptakis-(2,6-di-O-methyl)-β-cyclodextrin could be demonstrated. Space time yields of 120 g/(Ld) were obtained under not yet optimized conditions during the production of (S)-1-(2-naphthyl)-ethanol." @default.
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- W2079138217 date "1999-05-01" @default.
- W2079138217 modified "2023-10-13" @default.
- W2079138217 title "Asymmetric reductions in aqueous media: enzymatic synthesis in cyclodextrin containing buffers" @default.
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- W2079138217 doi "https://doi.org/10.1016/s0957-4166(99)00137-8" @default.
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