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- W2079138423 abstract "Abstract Polymerizing pseudo-crown ethers in the pores of a 70 μm thick polyethylene membrane support produced polymeric fixed site carrier membranes for facilitated transport separations. Pseudo-crown ethers were synthesized from the photopolymerization of metal : poly(ethylene glycol 200) diacrylate (PEG200DA) complexes. The metal:monomer complex led to a near-circular conformation of the monomer in which the two reactive endgroups were in close proximity; thus, the probability of intramolecular cyclization (i.e. pseudo-crown ether formation) was increased. Facilitated transport membranes using pseudo-crown ethers as carrier species were selective for alkali metals over transition and lanthanide metals. The K over Na selectivity was as high as 1.5, while the selectivity of K over Nd3+ was as high as 3700. The flux and selectivity of metal ions were a function of carrier concentration and type as well as the cross-linking of the pseudo-crown ether network." @default.
- W2079138423 created "2016-06-24" @default.
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- W2079138423 date "2000-04-15" @default.
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- W2079138423 title "Pseudo-crown ethers as fixed site carriers in facilitated transport membranes" @default.
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- W2079138423 doi "https://doi.org/10.1016/s0376-7388(99)00307-5" @default.
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