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- W2079145469 abstract "The principal methods for the investigation of outer-sphere interactions in solutions of labile inner-sphere complexes are arranged systematically and analysed. The modern views on the thermodynamics and structure of outer-sphere complexes are discussed and the reliability of certain hypotheses and models is examined from the standpoint of the comparison of the results of different experimental methods and theoretical ideas. A number of features of the outer-sphere interaction in solutions are formulated in relation to outer-sphere associated species formed by 3d metals, using certain data about the associated species of s, p, and f metals as well as outer-sphere associated species of inert complex cations. The bibliography includes 203 references." @default.
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- W2079145469 date "1980-07-31" @default.
- W2079145469 modified "2023-09-24" @default.
- W2079145469 title "Outer-sphere Interactions in Solutions of Labile Complexes" @default.
- W2079145469 doi "https://doi.org/10.1070/rc1980v049n07abeh002493" @default.
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