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- W2079145890 abstract "The increase in paramagnetism upon reaction is, under certain conditions, greater than can be explained on the basis of changes in the electronic configurations of the prosthetic groups. The difference is attributed to the formation of substrate free radicals. The effects of pH, temperature, and concentration of substrate and product on the rate of production of uric acid were studied. The kinetic data at pH 8.3 and 25° were described in terms of true Michaelis constants for xanthine and oxygen of 36 · 10−6M and 240 · 10−6M, respectively. The degree of anaerobic reduction by xanthine of enzyme flavin, as estimated spectrophotometrically, depends upon the concentration of enzyme. A mechanism is presented that embraces the manifold properties of this reaction." @default.
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- W2079145890 date "1962-01-01" @default.
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- W2079145890 title "Magnetic and spectrophotometric studies of the kinetics of the catalysis of xanthine oxidation by xanthine oxidase from cow's milk" @default.
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- W2079145890 doi "https://doi.org/10.1016/0006-3002(62)90591-7" @default.
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