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• W2079149588 abstract "Evidence for various types of compositional asymmetries associated with the interphase region of microphase-separated block copolymers leads to a classification of four general cases that may exist. The recently modified version of the Leary-Williams thermodynamic model for diblock (AB) and triblock (ABA) copolymers is extended to include all four cases, for planar microstructures. Calculations are performed of free energy and separation temperature corresponding to each case. Results are consistent with experimental observations of interphases found to be rich in the A component, but inconsistent with experiments that indicate residual mixing of B material in the A core. The inference is made that the latter observations correspond to samples that are not in a state of thermodynamic equilibrium." @default.
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• W2079149588 date "1985-12-01" @default.
• W2079149588 modified "2023-10-17" @default.
• W2079149588 title "Asymmetric composition profiles in block copolymer interphases: 2. Thermodynamic model predictions and implications" @default.
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• W2079149588 doi "https://doi.org/10.1016/0032-3861(85)90183-1" @default.
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