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- W2079161439 abstract "Gas phase catalytic oxidation of ethyl acetate and toluene was examined over copper modified ZSM-5 catalysts under atmospheric pressure. Nanostructure of ZSM-5 was characterized by XRD, SEM and TEM techniques. Elemental composition of ZSM-5 was determined using EDX, ICP-AES and XPS techniques. Results of catalytic studies showed better catalytic activity of Cu-ZSM-5 catalysts than those of parent ZSM-5 and HZSM-5, which revealed catalytic role of copper ions in the Cu-ZSM-5 catalysts. Effects of some parameters over catalytic conversion of these compounds were also studied. Ethyl acetate showed more reactivity than toluene over the Cu-ZSM-5 catalysts. Furthermore, the catalytic activity of Cu-ZSM-5 catalysts increased with increasing the copper loadings. The conversion behavior of a binary mixture of ethyl acetate and toluene was different from that of a single form. A promotive and inhibitive behavior was observed for conversion of ethyl acetate and toluene in the binary mixture, respectively. Water vapor as co-feed had an inhibitive effect on conversion of organic compounds over the Cu-ZSM-5 catalysts." @default.
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- W2079161439 date "2010-02-01" @default.
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- W2079161439 title "Nanostructure Copper-exchanged ZSM-5 Catalytic Activity for Conversion of Volatile Organic Compounds (Toluene and Ethyl Acetate)" @default.
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- W2079161439 doi "https://doi.org/10.1002/cjoc.201090045" @default.
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