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- W2079166000 abstract "We have investigated by means of HREEL spectroscopy electron induced reactivity in a binary CO2 : NH3 ice mixture. It was shown that the interaction of low energy electrons (9–20 eV) with such mixtures induces the synthesis of neutral carbamic acid NH2COOH and that flashing the sample at 140 K induces the formation of ammonium carbamate. The products have been assigned by FTIR spectroscopy of a CO2 : NH3 mixture heated from 10 K to 240 K. A mechanism involving dissociation of NH3 molecules into NH2˙ and H˙ radicals is proposed to explain the product formation." @default.
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- W2079166000 date "2009-01-01" @default.
- W2079166000 modified "2023-10-18" @default.
- W2079166000 title "Chemistry induced by low-energy electrons in condensed multilayers of ammonia and carbon dioxide" @default.
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- W2079166000 doi "https://doi.org/10.1039/b812796d" @default.
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