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- W2079169096 abstract "The gel chromatographic behaviours of six β-diketones and their metal complexes, particularly chromium complexes, have been investigated by thin-layer chromatography in dioxan and benzene media at 25 +− 1°. The effects of several development conditions of the RF values are not marked, the systems yielding very reproducible RF values for β-diketones and their complexes. For both eluents, each β-diketone exhibits a lower RF value than its chromium complex, which suggests that the sieving effect may be a dominant factor for the chromatographic process. A plot of log ((1/RF — 1) vs.Kvs. obtained by a precise column method yields a straight line with a slope of unity, indicating that the thin-layer chromatographic elution proceeds under conditions very close to the precise column chromatography." @default.
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- W2079169096 date "1978-12-01" @default.
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- W2079169096 title "Thin-layer chromatography of various β-diketones and their metal complexes on styragel 60A" @default.
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- W2079169096 doi "https://doi.org/10.1016/s0021-9673(00)92267-2" @default.
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